Ester-Directed Alkene Functionalization. A Potential Approach to Trichothecene Synthesis
Construction of potential key intermediate 3b for trichothecene synthesis is explored, on the basis of an ester-assisted alkene functionalization, which leads to a short synthesis of lactone 3a.Evaluation of the directing effect of ester functionality on epoxidation of a neighboring double bond was carried out by using a number of cyclohexene and cycloheptene derivatives.
Pearson, Anthony J.,Hsu, Shih-Ying
p. 2505 - 2511
(2007/10/02)
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