- Reductive dehalogenation of polyhalofluorocarbons with tributyltin hydride
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The reduction of polyhalofluorocarbons, including ClCF2CFClCF2Cl, (ClCF2CFCl)2, ICH2(CF2)3CH2I and vicinal dichloroperfluorocycloalkanes, with tributyltin hydride gave the corresponding hydrofluorocarbons in good to excellent yield.The results are compared with similar reductions with other reducing agents, and to tin hydride reductions of non-fluorinated analogs. - Keywords: Reductive dehalogenation; Polyfluorocarbons; Tributyltin hydride; NMR spectroscopy; Hydrofluorocarbons
- Puy, Michael Van Der,Belter, Randolph K.,Borowski, Ralph J.,Ellis, Lois A. S.,Persichini, Phillip J.,et al.
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