22577-15-7

Basic information

• Product Name: 3-ALLYLOXYPROPIONIC ACID
• Synonyms: 3-ALLYLOXYPROPIONIC ACID;RARECHEM AL BO 0451;Allyloxypropionicacid;3-(Allyloxy)propanoic acid;3-ALLYLOXYPROPIONIC ACID 95+%;3-(Allyloxy)
• CAS NO: 22577-15-7
• Molecular Formula: C₆H₁₀O₃
• Molecular Weight: 130.14
• Mol File: 22577-15-7.mol

Chemical Properties

• Boiling Point: 192 °C
• Flash Point: 91.7 °C
• Appearance: /
• Density: 1.06
• Refractive Index: 1.4400-1.4430
• Storage Temp.: Refrigerator
• PKA: 4.36±0.10(Predicted)
• CAS DataBase Reference: 3-ALLYLOXYPROPIONIC ACID(CAS DataBase Reference)
• NIST Chemistry Reference: 3-ALLYLOXYPROPIONIC ACID(22577-15-7)
• EPA Substance Registry System: 3-ALLYLOXYPROPIONIC ACID(22577-15-7)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36/37/39
• Hazardous Substances Data: 22577-15-7(Hazardous Substances Data)

Usage

Uses

Used in Chemical Industry:
3-Allyloxypropionic Acid is used as an intermediate for the synthesis of various chemicals, including plasticizers, which are additives that increase the plasticity or flexibility of materials, particularly in the plastics industry. Its allyl group allows for further chemical modifications and reactions, making it a versatile building block for the development of new compounds and materials.
Used in Plasticizers Production:
3-Allyloxypropionic Acid is used as a key component in the production of plasticizers, which are widely utilized in the manufacturing of polymers and plastics to enhance their workability, flexibility, and durability. The allyl group in 3-allyloxypropionic acid can be further reacted to produce plasticizers with specific properties tailored to various applications, such as in the automotive, construction, and packaging industries.

Upstream product

• 107-18-6 allyl alcohol 
• 107-13-1 acrylonitrile 
• 6180-67-2 3-allyloxy-1-propanol 
• 93639-67-9 1-(allyloxy)-2-(methoxycarbonyl)ethane 
• 5331-41-9 allyl 3-(allyloxy)propanoate 
• 57-57-8 β-Propiolactone 
• 3088-44-6 3-allyloxy-propionitrile 

Downstream Products

• 119124-52-6 Se-Phenyl 4-Oxaselenohept-6-enoate 

Relevant articles and documents

Preparation of 3-(n-alkenoxy)propanoic acids

3-(n-Alkenoxy)propanoic acids have been prepared by reaction of alkenols with tert-butyl acrylate (catalyzed by Triton B or n-butyl lithium) followed by cleavage of the tert-butyl group by CF3COOH or KO2.

Organoselenium and DMAP co-catalysis: Regioselective synthesis of medium-sized halolactones and bromooxepanes from unactivated alkenes

A catalytic system consisting of bis(4-methoxyphenyl)selenide and 4-(dimethylamino)pyridine (DMAP) has been developed for the regioselective synthesis of medium-sized bromo/iodo lactones and bromooxepanes possessing high transannular strain. 77Se NMR, mass spectrometry and theoretical studies reveal that the reaction proceeds via a quaternary selenium intermediate.

Oxidative cyclization of alkenoic acids promoted by AgOAc

Alkenoic acids derived from salicylic acid and analogues undergo an unexpected oxidative cyclization process triggered by AgOAc leading to 4H-benzo[d][1,3]dioxin-4-ones. The process is affected by the substitution on the aryl and the allyl units.

Stereodivergent organocatalytic intramolecular michael addition/ lactonization for the asymmetric synthesis of substituted dihydrobenzofurans and tetrahydrofurans

A stereodivergent asymmetric Lewis base catalyzed Michael addition/lactonization of enone acids into substituted dihydrobenzofuran and tetrahydrofuran derivatives is reported. Commercially available (S)-(-)-tetramisole hydrochloride gives products with hi

Kinetics of the Coupling Reactions of the Nitroxyl Radical 1,1,3,3-Tetramethylisoindoline-2-oxyl with Carbon-Centered Radicals

Radical clocks have been used to study the kinetics of the coupling of the nitroxyl radical 1,1,3,3-tetramethylisoindoline-2-oxyl (T) in cyclohexane or benzene with a variety of carbon-centered radicals including simple unhindered primary, secondary, and