Supramolecular Photocatalysis by Utilizing the Host–Guest Charge-Transfer Interaction: Visible-Light-Induced Generation of Triplet Anthracenes for [4+2] Cycloaddition Reactions
Supramolecular photocatalysis via charge-transfer excitation of a host–guest complex was developed by use of the macrocyclic boronic ester [2+2]BTH-F containing highly electron-deficient difluorobenzothiadiazole moieties. In the presence of a c