Asymmetric hydrogenation of enol phosphinates by iridium catalysts having N,P ligands
Enol phosphinates, which are structural analogues of enol acetates, have for the first time been employed as substrates for Ir-catalyzed asymmetric hydrogenation. A number of enol phosphinates have been synthesized and reduced successfully with up to and above 99% ee.
Cheruku, Pradeep,Gohil, Suresh,Andersson, Pher G.
p. 1659 - 1661
(2008/02/02)
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