Total syntheses of 2,2′-epi-cytoskyrin A, rugulosin, and the alleged structure of rugulin
The total syntheses of 2,2′-epi-cytoskyrin A, rugulosin, and the alleged structure of rugulin are described. These naturally occurring bisanthraquinones and their relatives are characterized by novel molecular architectures at the core, at which lies a mo
Nicolaou,Yee, Hwee Lim,Piper, Jared L.,Papageorgiou, Charles D.
p. 4001 - 4013
(2008/02/04)
Total synthesis of (+)-rugulosin and (+)-2,2′-epi-cytoskyrin A through cascade reactions
(Chemical Equation Presented) The cytoskyrin cascade: The total syntheses of the bisanthraquinones 2 (+)-2,2′-epi-cytoskyrin A (R2 = OMe) and (+)-rugulosin (R2 = Me) has been achieved through a cascade sequence from anthradihydroquin
Nicolaou,Lim, Yee Hwee,Papageorgiou, Charles D.,Piper, Jared L.
p. 7917 - 7921
(2007/10/03)
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