Transition metal complexes with wide-angle dithio-, diseleno- and ditelluroethers: Properties and structural systematics
The ligands o-C6H4(CH2EMe)2 (E = S or Se) have been prepared and characterised spectroscopically. A systematic study of the coordination chemistry of these, together with the telluroether analogue, o-C6/su
Levason, William,Nirwan, Manisha,Ratnani, Raju,Reid, Gillian,Tsoureas, Nikolaos,Webster, Michael
p. 439 - 448
(2008/01/27)
One-Flask Synthesis of Sulfides from Alcohols and Alkyl Halides Using Benzoxazoline-2-thione
The synthesis of sulfides from alcohols and benzoxazoline-2-thione (I) was studied to establish its generality and the mechanism of the reaction.A one-flask synthesis of sulfides from alcohols was developed.According to this procedure, various sulfides were prepared without the use of illsmelling thiols.Moreover, partial sulfenylation of diols to give sulfenyl alcohols was achieved.Keywords - one-flask synthesis; benzoxazoline-2-thione; partial sulfenylation; sulfide; sulfenyl alcohol