Reactions Involving Fluoride Ion. Part 40. Amines as Initiators of Fluoride Ion Catalysed Reactions
Tetrakis(dimethylamino)ethene (TDAE) and trimethylamine react with anhydrous unsaturated fluorocarbons to produce, 'in situ', powerful fluoride-ion sources.These are used to iniate carbon-carbon bond forming reactions eg. oligomerisation and polyfluoroalkylation, and many of these reactions occur efficiently in the absence of a solvent.
Chambers, Richard D.,Gray, William K.,Korn, Stewart R.
p. 13167 - 13176
(2007/10/03)
More Articles about upstream products of 24813-57-8