25032-49-9

Basic information

• Product Name: DI-T-BUTYL(I-PROPYL)PHOSPHINE
• Synonyms: DI-TERT-BUTYLISOPROPYLPHOSPHINE;DI-T-BUTYL(I-PROPYL)PHOSPHINE;Di-t-butyl(i-propyl)phosphine,min.98%;Di-t-butyl(i-propyl)phosphine, min. 98%;Bis(1,1-dimethylethyl)(1-methylethyl)phosphine;98% (t-Bu)2(i-Pr)P;Di-t-butyl(i-propyl)phosphine,98% (t-Bu)2(i-Pr)P
• CAS NO: 25032-49-9
• Molecular Formula: C11H25P
• Molecular Weight: 188.29
• Product Categories: organophosphine ligand;Achiral Phosphine;Alkyl Phosphine
• Mol File: 25032-49-9.mol

Chemical Properties

• Appearance: colorless/liquid
• CAS DataBase Reference: DI-T-BUTYL(I-PROPYL)PHOSPHINE(CAS DataBase Reference)
• NIST Chemistry Reference: DI-T-BUTYL(I-PROPYL)PHOSPHINE(25032-49-9)
• EPA Substance Registry System: DI-T-BUTYL(I-PROPYL)PHOSPHINE(25032-49-9)

Safety Data

• Hazardous Substances Data: 25032-49-9(Hazardous Substances Data)

Usage

Uses

Used in Organic Synthesis:
DI-T-BUTYL(I-PROPYL)PHOSPHINE is used as a reducing agent for various organic synthesis processes. Its reducing properties make it a valuable component in the production of different organic compounds.
Used in Chemical Research:
In the field of chemical research, DI-T-BUTYL(I-PROPYL)PHOSPHINE is used as a reagent for studying the properties and reactions of organophosphorus compounds. Its unique structure and reactivity provide insights into the behavior of phosphorus-containing molecules.
Used in Pharmaceutical Industry:
DI-T-BUTYL(I-PROPYL)PHOSPHINE is used as an intermediate in the synthesis of certain pharmaceutical compounds. Its ability to act as a reducing agent is crucial in the production of specific drugs.
Used in Material Science:
In material science, DI-T-BUTYL(I-PROPYL)PHOSPHINE is used as a precursor in the development of new materials with unique properties. Its role in organic synthesis contributes to the creation of novel materials with potential applications in various industries.

Upstream product

• 74011-92-0 Tri(tert-butyl)isopropylidenphosphoran 
• 13716-12-6 tri-tert-butyl phosphine 
• 74011-90-8 Tri(tert-butyl)ethylidenphosphoran 
• 13716-10-4 di(tert-butyl)chlorophosphine 
• 1068-55-9 isopropylmagnesium chloride 

Downstream Products

• 1239667-52-7 [(t-Bu)2(i-Pr)PH][HB(p-C₆F₄H)3] 

Relevant articles and documents

Combining the reactivity properties of pcy3 and P t Bu3 into a single ligand, P(i Pr)(t Bu)2. reaction via mono- or bisphosphine palladium(0) centers and palladium(i) dimer formation

Trialkylphosphine ligands are ubiquitous in catalysis. Via modulation of the steric bulk of these ligands, two central aspects that dictate reactivity and selectivity in catalysis can be controlled: i.e., the coordination sphere and favored oxidation stat

PROCESS FOR PRODUCING TERTIARY PHOSPHINE HAVING BULKY HYDROCARBON GROUP BONDED

The present invention provides a production process by which tertiary phosphine with an attached sterically bulky hydrocarbon group, said tertiary phosphine being useful as a ligand of a transition metal catalyst in organic synthesis reactions, can be produced in a high yield and with high purity on an industrial scale through simple and safe operations. The present invention comprises allowing a dialkylphosphinous halide to react with a Grignard reagent in the presence of a copper compound in an amount corresponding to 0.1 to 5% by mol based on the dialkylphosphinous halide to produce tertiary phosphine represented by the following formula (3) : wherein R1 and R2 are each a tertiary hydrocarbon group of 4 to 13 carbon atoms, and R3 is an alkyl group, an alkenyl group, an aryl group or the like.

Extreme Steric Hindrance: Synthesis and Structure of the Tetra(tert-butyl)phosphonium Cation - a Case of T-Symmetry

Starting from 3P and following a series of quaternisation and ylidation steps under carefully controlled conditions, the 4P+ cation could be synthesized for the first time: 3P -> 3PCH3+ -> 3P=CH2 -> 3PCH2CH3+ -> 3P=CHCH3 -> 3PCH(CH3)2+ -> 3P=C(CH3)2 -> 4P+.All intermediates were isolated.The tetra(tert-butyl)phosphonium cation was further characterized in the form of the iodide and tetrafluoroborate by means of all spectroscopic methods available.An X-ray diffraction analysis of the BF4 salt showed a face-centered cubic lattice with a superstructure (space group F - Td5).The cation has T-symmetry as predicted by theoretical force field calculations with a tert-butyl twist of 14 deg.Due to the extreme steric hindrance, the P - C bond distances are elongated and the C-C-C angles compressed.