Stereocontrolled total synthesis of (+)-tutin and (+)-asteromurin A, toxic picrotoxane sesquiterpenes
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Wakamatsu,Kigoshi,Niiyama,et al.
p. 5551 - 5558
(2007/10/02)
STEREOCONTROLLED TOTAL SYNTHESIS OF (+)-TUTIN, A TOXIC SESQUITERPENE OF PICROTOXANE-TYPE
The first total synthesis of (+)-tutin (1), a toxic sesquiterpene of picrotoxane-type isolated from the poisonous plants of the Coriaria species is described.