A kinetic and nuclear magnetic resonance study of methylated pyrimidine nucleosides
Alkylated pyrimidine nucleosides are of interest from the viewpoint of mutagenesis and carcinogenesis. (1)H and (13)C nmr data are presented for a series of 2'-deoxynucleosides methylated at the O2-, O4-, and N3-positions of the base, and discussed in terms of their physical properties.The pH dependence of the stability of the O2- and O4-methylated 2'-deoxyribosides as well as the corresponding ribosides was examined by (1)H nmr and ultraviolet (uv) spectrophotometric methods.
Allore, B. D.,Queen, A.,Blonski, W. J.,Hruska, F. E.
p. 2397 - 2402
(2007/10/02)
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