INTEGRATED METHODS AND SYSTEMS FOR PRODUCING AMIDE AND NITRILE COMPOUNDS
Provided herein are integrated methods and systems for the production of acrylamide and acrylonitrile compounds and other compounds from at least beta-lactones and/or beta-hydroxy amides.
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Paragraph 00089-00092; 00099
(2020/09/30)
Efficient nitrile hydration mediated by RuII catalysts in micellar media
Efficient nitrile hydration to the corresponding amide derivatives is observed in water using poorly soluble [RuCl2(η6- arene)(PR3)] catalysts 1 with the aid of surfactants to ensure substrate and catalyst solubilization, and enabling ligand effect study on catalytic activity. Amide yields of 40 to 95% can be observed with a variety of aromatic and aliphatic nitriles using the optimized catalyst system, [RuCl 2(p-cymene)(PPh2OEt)]/Triton X-114. Catalyst separation and recycling is possible.
Cavarzan, Alessandra,Scarso, Alessandro,Strukul, Giorgio
experimental part
p. 790 - 794
(2010/09/05)
KINETICS OF THE FORMATION OF β-HYDROXYPROPIONIC ACID FROM ETHYLENE CYANOHYDRIN
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Chubarov, G. A.,Danov, S. M.,Logutov, V. I.,Brovkina, G. V.,Kolesnikov, V. A.
p. 1101 - 1104
(2007/10/02)
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