26627-77-0Relevant articles and documents
Palladium catalyzed N-alkylation of amines with alcohols
Zhang, Yan,Qi, Xiujuan,Cui, Xinjiang,Shi, Feng,Deng, Youquan
scheme or table, p. 1334 - 1338 (2011/03/22)
An iron oxide immobilized palladium catalyst was prepared for the N-alkylation of amines with alcohols under base and organic ligand free conditions. Applying the optimized reaction conditions, the coupling reactions of amines and alcohols with various structures could be realized with up to 99% isolated yields. The catalysts were studied by XRD, BET, and XPS and the mechanism was studied by DFT calculations.
Direct and indirect reductive amination of aldehydes and ketones with solid acid-activated sodium borohydride under solvent-free conditions
Byung, Tae Cho,Sang, Kyu Kang
, p. 5725 - 5734 (2007/10/03)
A simple and convenient procedure for reductive amination of aldehydes and ketones using sodium borohydride activated by boric acid, p-toluenesulfonic acid monohydrate or benzoic acid as reducing agent under solvent-free conditions is described.