cas 271583-17-6, AMINO-(2-METHOXY-PHENYL)-ACETIC ACID | Articles data ｜lookchem

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271583-17-6

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ISOINDOLIN-1-ON DERIVATIVE, METHOD FOR PREPARING SAME, AND PHARMACEUTICAL COMPOSITION COMPRISING SAME AS EFFECTIVE COMPONENT FOR PREVENTING OR TREATING CANCER
The present invention relates to an isoindolin-1-one derivative, a method for preparing the same, and a pharmaceutical composition comprising the same as an active ingredient for preventing or treating cancer, wherein the isoindolin-1-one derivative exhib
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Paragraph 0092; 0094

(2021/06/25)

Synthesis of Unprotected 2-Arylglycines by Transamination of Arylglyoxylic Acids with 2-(2-Chlorophenyl)glycine
The transamination of α-keto acids with 2-phenylglycine is an effective methodology for directly synthesizing unprotected α-amino acids. However, the synthesis of 2-arylglycines by transamination is problematic because the corresponding products, 2-arylglycines, transaminate the starting arylglyoxylic acids. Herein, we demonstrate the use of commercially available l-2-(2-chlorophenyl)glycine as the nitrogen source in the transamination of arylglyoxylic acids, producing the corresponding 2-arylglycines without interference from the undesired self-transamination process.
Inada, Haruki,Shibuya, Masatoshi,Yamamoto, Yoshihiko
p. 11047 - 11059
(2020/10/12)

A facile synthesis of substituted phenylglycines
A convenient scaleable process for the preparation of substituted phenylglycines 2 by a modified Strecker reaction is described. Bisulfite- mediated addition of benzylamine and cyanide anion to substituted benzaldehydes 3 gave the aminonitriles 4 which were hydrolysed in two steps to the N-protected amino acid 1. Debenzylation using catalytic transfer hydrogenation gave the title compounds in good yield.
Davies, Antony J.,Ashwood, Michael S.,Cottrell, Ian F.
p. 1095 - 1102
(2007/10/03)

SYNTHESIS OF 2,3-BENZO-1-OXAOCTEM-4-CARBOXYLIC ACID
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Daum, S. J.,Hansen, P. E.
p. 1 - 6
(2007/10/02)

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Chemical Properties

Boiling Point: 343.9°Cat760mmHg
Flash Point:161.8°C
Density: 1.246g/cm³
Storage Temp.:Keep in dark place,Inert atmosphere,Room temperature
Vapor Pressure: 2.6E-05mmHg at 25°C
PKA: 1.78±0.10(Predicted)
PSA: 72.55000
LogP: 1.47990

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