272443-24-0

Basic information

• Product Name: Ethanone, 1-[3-(methylamino)-2-pyridinyl]- (9CI)
• Synonyms: Ethanone, 1-[3-(methylamino)-2-pyridinyl]- (9CI);1-(3-(Methylamino)pyridin-2-yl)ethanone
• CAS NO: 272443-24-0
• Molecular Formula: C8H10N2O
• Molecular Weight: 150.1778
• Product Categories: PYRIDINE;ACETYLGROUP
• Mol File: 272443-24-0.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Ethanone, 1-[3-(methylamino)-2-pyridinyl]- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-[3-(methylamino)-2-pyridinyl]- (9CI)(272443-24-0)
• EPA Substance Registry System: Ethanone, 1-[3-(methylamino)-2-pyridinyl]- (9CI)(272443-24-0)

Safety Data

• Hazardous Substances Data: 272443-24-0(Hazardous Substances Data)

Upstream product

• 272443-23-9 1,3-dimethyl-1,3-dihydro-isothiazolo[4,3-b]pyridine 2,2-dioxide 
• 6298-19-7 2-chloro-3-aminopyridine 
• 272443-20-6 N-(2-chloro-3-pyridyl)ethanesulfonamide 
• 272443-22-8 N-(2-chloro-3-pyridyl)-N-methylethanesulfonamide 
• 1027383-06-7 C₉H₁₃ClN₂O₄S₂ 

Relevant articles and documents

Reactions of pyridine analogues of aza-ortho-xylylenes generated from 1,3-dialkylpyridosultams

2,3-Dihydro-3-imino-2-methylenepyridines, generated by thermal extrusion of SO2 from 1,3-dialkyl-1,3-dihydroisothiazolo[4,3-b]pyridine 2,2-dioxides (1,3-dialkylpyridosultams), underwent [1,5] hydrogen shifts, which led to 3- alkylamino-2-vinylpyridine derivatives. Cycloalkanespiro-3-pyridosultams 12, which were easily obtained by alkylation of pyridosultams with α,ω- dihaloalkanes, gave, in a similar reaction, 3-alkylamino-2- cycloalkenylpyridine derivatives 14 in good yields. Cyclobutanespiro-3- pyridosultam 12b, after thermal extrusion of SO2, formed cyclobutenyl derivative 14b, which underwent a ring-opening reaction to form butadiene derivative 15. The latter can be trapped with dienophiles, for example, N- phenylmaleimide.