- SUBSTITUTION AND ADDITION REACTIONS OF ORGANIC SUBSTRATES WITH HYPOFLUOROUS ACID
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The chemical reactions of hypofluorous acid with aromatic and olefinic substrates show considerable variety.Hypofluorous acid reacts with naphthalene to give 1-naphthol, 2-naphthol and 1,4-naphthoquinone: with benzothiophen to give the 1,1-dioxide; with trans-stilbene to give threo-2-fluoro-1-hydroxy-1,2-diphenylethane, benzophenone and diphenylacetaldehyde: and with cholesteryl acetate to give the two epoxides ( α:β=6.3:1 ) and two fluorohydrins ( 6β-fluoro-5-β-ol and 5α-fluoro-6β-ol ).
- Andrews, Laura E.,Bonnett, Raymond,Appelman, Evan H.
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p. 781 - 784
(2007/10/02)
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