Divergent reaction pathways in amine additions to β-lactone electrophiles. An application to β-peptide synthesis
β-Lactone electrophiles are subject to regioselective addition-elimination (AE) or SN2 ring opening with various nitrogen-based nucleophiles. Primary and secondary amines promote AE ring opening to deliver products that are the functional equiv
Nelson, Scott G.,Spencer, Keith L.,Cheung, Wing S.,Mamie, Steven J.
p. 7081 - 7091
(2007/10/03)
Enantioselective β-amino acid synthesis based on catalyzed asymmetric acyl halide-aldehyde cyclocondensation reactions
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Nelson, Scott G.,Spencer, Keith L.
p. 1323 - 1325
(2007/10/03)
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