27944-79-2Relevant articles and documents
MANUFACTURING METHOD FOR THE ALDEHYDE BY HYDROFORMYLATION REACTION
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Paragraph 0079-0081; 0083-0084; 0101, (2021/07/13)
A phosphine ligand represented by chemical formula 1. Transition metal catalyst A hydroformylation catalyst composition comprising a solvent and a solvent. Provided is a process for preparing aldehydes by hydroformylation using olefinic compounds and formaldehyde to produce aldehydes.
Polymer-mediated pinacol rearrangements
Pavlik, Christopher,Morton, Martha D.,Smith, Michael B.
experimental part, p. 2191 - 2194 (2011/11/06)
Both poly(3,4-ethylenedioxythiophene) and poly(pyrrole) mediate a pinacol rearrangement of 1,2-diols. The yields of ketone or aldehyde products are comparable to those observed for treatment with mineral acids or Lewis acids. The advantage of this protocol is a two-phase reaction medium in hydrocarbon solvents that allows facile recovery of the products by simple filtration of the polymer and removal of solvents. Both the polymer and the hydrocarbon solvent may be recovered and used in subsequent reactions. Georg Thieme Verlag Stuttgart · New York.
ADDITION RADICALAIRE DU PROPANAL A DIVERS ALCENES ET CYCLENES : ASPECTS STERIQUES ET POLAIRES
Tabbaa, I.,Cazaux, M.,Lalande, R.
, p. 1011 - 1018 (2007/10/02)
Free radical addition of propanal to double bonds, initiated by benzoyl peroxide, mainly leads to two adducts, an aldehyde and a ketone, when the double bond has a methylene group ; these results are explained in terms of polar effects in the free radical transfert reactions.When the double bond has no methylene group, only the ketonic adduct is obtained ; the steric effects in the free radical addition step explain these results.