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  • 28401-39-0 Structure
  • Basic information

    1. Product Name: FRONTALIN
    2. Synonyms: (1S,5R)-1,5-Dimethyl-6,8-dioxabicyclo[3.2.1]octane
    3. CAS NO:28401-39-0
    4. Molecular Formula: C8H14O2
    5. Molecular Weight: 142.2
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 28401-39-0.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 167.3°Cat760mmHg
    3. Flash Point: 53.4°C
    4. Appearance: /
    5. Density: 1.056g/cm3
    6. Vapor Pressure: 2.25mmHg at 25°C
    7. Refractive Index: 1.479
    8. Storage Temp.: N/A
    9. Solubility: N/A
    10. CAS DataBase Reference: FRONTALIN(CAS DataBase Reference)
    11. NIST Chemistry Reference: FRONTALIN(28401-39-0)
    12. EPA Substance Registry System: FRONTALIN(28401-39-0)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 28401-39-0(Hazardous Substances Data)

28401-39-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 28401-39-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,8,4,0 and 1 respectively; the second part has 2 digits, 3 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 28401-39:
(7*2)+(6*8)+(5*4)+(4*0)+(3*1)+(2*3)+(1*9)=100
100 % 10 = 0
So 28401-39-0 is a valid CAS Registry Number.
InChI:InChI=1/C8H14O2/c1-7-4-3-5-8(2,10-7)9-6-7/h3-6H2,1-2H3

28401-39-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name frontalin

1.2 Other means of identification

Product number -
Other names FRONTALIN

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:28401-39-0 SDS

28401-39-0Relevant articles and documents

ENZYMATIC KINETIC RESOLUTION OF CYANOHYDRIN ACETATES AND ITS APPLICATION TO THE SYNTHESIS OF (S)-(-)-FRONTALIN

Ohta, Hiromichi,Kimura, Yoichi,Sugano, Yasushi,Sugai, Takeshi

, p. 5469 - 5476 (2007/10/02)

Kinetic resolution of racemic 1-cyano-1-methylalkyl and alkenyl acetates has been achieved on incubation with Pichia miso IAM 4682, which hydrolyzed selectively the (R)-enantiomer, leving behind the (S)-enantiomer intact.The chiral 1-cyano-1-methyl-5-hexenyl acetate thus obtained was converted to (S)-frontalin via unsaturated diol.

SYNTHESIS OF THE PHEROMONES, (E)-3,7-DIMETHYL-2,7-OCTADIENYL PROPIONATE, (E)-3,7-DIMETHYL-2-OCTENE-1,8-DIOL AND FRONTALIN FROM A COMMON INTERMEDIATE

Dhokte, U. P.,Rao, A. S.

, p. 811 - 822 (2007/10/02)

Ketal ester 9 has been prepared in five steps from methyl levulinate 4 (scheme 1).The propionate 1, diol 2 and (+/-) frontalin 3 were prepared from ester 9 employing the routes shown in scheme 2,3 and 4 respectively.The branched chain alkenes 13 and 20 were prepared conveniently from the primary alcohols 11 and 10 following the procedure of S.Wolff.Triethyl phosphonopropionate 7 has been prepared by methylating triethylphosphonoacetate with methyl iodide in the presence of sodium hydride.

CONVENIENT SYNTHETIC ROUTE TO (+/-) -FRONTALIN

Kongkathip, Boonsong,Sokkho, Rongsan,Kongkathip, Ngampong

, p. 1849 - 1850 (2007/10/02)

(+/-)-Frontalin was synthesized in a few steps sequence starting from ethyl acetoacetate involving intramolecular cyclization using palladium chloride as catalyst

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