Thermal Addition of Alkanes to Alkenes. V. Addition of Cyclohexane to 1-Octene in a Free Radical Chain reaction at Supercritical Fluid Conditions
Alkanes can be added to alkenes in a thermally initiated free radical chain reaction ("ane reaction").Kinetic and mechanistic studies on the addition of cyclohexane (1) to 1-octene (2) (molar ratio = 100:1) at 330-450 deg C and pressures of up to 300 bar
Metzger, Juergen O.
p. 767 - 781
(2007/10/02)
Bildung von Alkylradikalen durch thermische bimolekulare Reaktion von Alkanen und Alkenen
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Metzger, Juergen O.
p. 914 - 915
(2007/10/02)
HOCHDRUCK-HOCHTEMPERATUR-REAKTIONEN IN EINEM STROEMUNGSREAKTOR-VI. THERMISCHE ADDITION VON ALKANEN AN ALKENE
The thermal Anti-Markownikow-addition of alkanes to activated and desactivated alkenes ("direkte substituierende Addition", "Ane-reaction") at 650-723 K and reaction times of 1-10 min. is described.
Metzger, Juergen,Hartmanns, Joerg,Koell, Peter
p. 1891 - 1894
(2007/10/02)
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