cas 2894-87-3, 2,3,5,6-TETRAFLUORO-4-(PENTAFLUOROPHENYL)PHENOL | Articles data ｜lookchem

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2894-87-3

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Pyrolysis reactions of nonafluorobiphenyl-4-yl prop-2-enyl ether: A remarkable rearrangement reaction of an intramolecular Diels-Alder product
The pyrolysis reaction of nonafluorobiphenyl-4-yl prop-2-enyl ether were studied. The reaction was proposed as a remarkable rearrangement reaction of an intramolecular Diels-Alder product. The flash vapor pyrolysis of the compound performed at 350 °C gave a complex mixture containing the products obtained from Diels-Alder reactions. The molecular structure of the compounds obtained was characterized by x ray crystallography.
Batsanov, Andrei S.,Brooke, Gerald M.,Holling, Darren,Kenwright, Alan M.
p. 1731 - 1734
(2000)
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Pyrolysis reactions of 4-nonafluorobiphenyl prop-2-enyl ether: A remarkable rearrangement reaction
The formation of the unexpected bicyclic compound 16 via the pyrolytic isomerisation of 4-nonafluorobiphenyl prop-2-enyl ether 8 can be rationalised by invoking the intermediacy of a rare retro-cyclisation reaction of the internal Diels-Alder adduct 12 (f
Batsanov, Andrei S.,Brooke, Gerald M.,Holling, Darren,Kenwright, Alan M.
p. 1549 - 1550
(1999)
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More Articles about upstream products of 2894-87-3

247135-68-8
Nonafluorobiphenyl-4-yl prop-2-enyl ether

Chemical Properties

Melting Point: 117-120oC(lit.)
Boiling Point: 236.3°C at 760 mmHg
Flash Point:96.7°C
Density: 1.738g/cm³
Vapor Pressure: 0.0311mmHg at 25°C
PKA: 4.54±0.33(Predicted)
PSA: 20.23000
LogP: 4.31110

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