- Preparation method of epoxy silane coupling agent
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The invention provides a preparation method of an epoxy silane coupling agent. The preparation method comprises the following steps: (1) synthesizing diallyl ether from chloropropene and allyl alcohol under the action of a catalyst and an alkali; (2) carrying out a hydrosilylation reaction on the diallyl ether and hydrogen-containing chlorosilane under the action of a platinum catalyst to obtain allyloxopropyl chlorosilane; (3) carrying out esterification reaction on the allyloxopropyl chlorosilane and saturated alcohol to obtain allyloxoalkoxy silane; and (4) carrying out epoxidation on the allyloxyalkoxy silane by using an oxidizing agent, so as to obtain gamma-(2, 3-epoxypropoxypropyl)alkoxy silane. The preparation method provided by the invention can be suitable for all gamma-(2, 3-epoxypropoxypropyl) epoxy silane, the used catalyst and raw materials are easy to obtain, the yield is high, and the industrial feasibility is high.
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Paragraph 0045; 0050
(2021/05/05)
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- FILM FORMING PERSONAL CARE COMPOSITIONS AND METHODS
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Compositions, kits and methods of preparing a biocompatible film for cosmetic or medical uses are disclosed. The compositions or kits contain polyvinyl acetal (PVA), siloxane and a solvent. The siloxane can have a hydrophilic group. Once the solvent content is reduced, for instance, by evaporation, the mixture of PVA and siloxane is solidified, forming a film. The compositions and kits, optionally, further include one or more of an antimicrobial agent, a pigment, an anti-inflammatory agent, an anesthetic agent or a hemostatic agent. Such a film can be used, for example, in the form of an antimicrobial sealant, a liquid bandage, body paints, scar camouflage, water-proof sun block, makeup sealer, or antimicrobial wipe or spray.
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- Unexpected silicon group transfer in difunctional alkoxy silanes
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During the hydrosilylation reaction of a difunctional silane with allyl glycidyl ether (AGE), two scrambled hydrosilylation products were produced in significant amounts. This scrambling is reaction condition dependent and has been observed in a few other examples. It appears to be the first such alkoxysilane transformation to occur under these conditions, although similar siloxane transformations have been documented. This also introduces a method of preparing certain organofunctional alkyldialkoxysilanes in high purities via hydrosilylation, where the close boiling rearrangement by-products are minimized.
- Filipkowski, Michelle A.,Petty, Herbert E.,Westmeyer, Mark D.,Schilling Jr., Curtis L.
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