CuI/DMPAO-catalyzed N-arylation of acyclic secondary amines
DMPAO has been found to be a powerful ligand to enable copper-catalyzed coupling of aryl halides with aliphatic acyclic secondary amines take place under relatively mild conditions, and coupling of aryl halides with primary amines and cyclic secondary amines proceeds at low catalyst loading.
Zhang, Yu,Yang, Xinye,Yao, Qizheng,Ma, Dawei
supporting information; experimental part
p. 3056 - 3059
(2012/07/28)
Synthesis, crystal structures and magnetic properties of M IICuII chains (M=Mn and Co) with sterically hindered alkyl-substituted phenyloxamate bridging ligands
A series of neutral oxamato-bridged heterobimetallic chains of general formula [MCu(Lx)2(S)2]·p S·q H2O [p=0-1, q=0-2.5; L1=N-2,6-dimethylphenyloxamate, S=DMF with M=Mn (1 a) and Co (1 b); L2/su