Studies on the stereoselective synthesis of the marine antitumor agent eleutherobin
(+)-Carvone has been converted into the sulfone 14 which comprises the left-hand side of the cytotoxic sesquiterpene, eleutherobin 1. Julia coupling of 14 to the aldehyde 21, followed by oxidation, dissolving metal reduction and stereoselective reduction
Carter, Rich,Hodgetts, Kevin,McKenna, Jeff,Magnus, Philip,Wren, Stephen
p. 4367 - 4382
(2007/10/03)
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