cas 2948-46-1, 1,4-Bis(1-methyl-1-hydroxyethyl)benzene | Articles data ｜lookchem

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2948-46-1

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Radical Reactions in Cavitands Unveil the Effects of Affinity on Dynamic Supramolecular Systems
Radical reduction of alkyl halides and aerobic oxidation of alkyl aromatics are reported using water-soluble container compounds (1 and 2). The reductions involve α,ω-dihalides (4-8 and 10) with radical initiators in cavitand hosts with varied binding affinities. Product distributions lead to general guidelines for the use of dynamic supramolecular systems with fast reactions. The binding of guest substrates in the hosts must show high affinities (Ka> 103M-1) to ensure that the reactions take place under confinement in the containers.
Angamuthu, Venkatachalam,Petroselli, Manuel,Rahman, Faiz-Ur,Rebek, Julius,Yu, Yang,Zhao, Xinluo
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(2020/02/18)

CATALYTIC DECOMPOSITION OF p-DIISOPROPYLBENZENE DIHYDROPEROXIDE
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Tsyskovskaya, I. V.,Potekhin, V. M.
p. 1262 - 1265
(2007/10/02)

New, bifunctional, active esters as potential bridging reagents for the 2 insulin chains
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Losse,Zapf,Schmidt,et al.
p. 438 - 439
(2007/10/02)

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Chemical Properties

Melting Point: 144-146 °C
Boiling Point: 298.5 °C at 760 mmHg
Flash Point:149.4 °C
Density: 1.051 g/cm³
Storage Temp.:Sealed in dry,Room Temperature
Vapor Pressure: 0.000567mmHg at 25°C
Refractive Index: 1.527
PKA: 14.25±0.29(Predicted)
PSA: 40.46000
LogP: 2.14140

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