Process for the preparation of medium sized carbocyclic alkyl ethers
An economically advantageous method is disclosed for the preparation without added solvent of a carbocyclic ether having from 10 to 16 carbon atoms in the ring of the formula STR1 wherein R is a straight or branched (C3 -C6) chain alkyl group or a benzyl group and n is from 5-11 carbon atoms, which method comprises: (1) reacting under an inert atmosphere a mixture consisting essentially of a carbocyclic alcohol of the formula STR2 wherein n is from 5-11 carbon atoms, about 1.5-10 molar equivalents of a straight or branch (C3 -C6) chain alkyl halide or benzyl halide and a metal hydride.
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(2008/06/13)
An Electrophile-Assisted Nonsolvent Synthesis of Alkyl Macroisocyclic Ethers: An Improved Nonsolvent Williamson Synthesis of Medium-Sized Alkyl Carbocyclic Ethers
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Chapman, John J.,Reid, Jack R.
p. 3757 - 3759
(2007/10/02)
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