301651-24-1

Basic information

• Product Name: 3a(4H)-Benzofuranamine,2-ethoxyhexahydro-N-methoxy-,(2S,3aS,7aR)-(9CI)
• Synonyms: 3a(4H)-Benzofuranamine,2-ethoxyhexahydro-N-methoxy-,(2S,3aS,7aR)-(9CI)
• CAS NO: 301651-24-1
• Molecular Formula: C11H21NO3
• Molecular Weight: 215.29
• Product Categories: ETHOXY
• Mol File: 301651-24-1.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3a(4H)-Benzofuranamine,2-ethoxyhexahydro-N-methoxy-,(2S,3aS,7aR)-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 3a(4H)-Benzofuranamine,2-ethoxyhexahydro-N-methoxy-,(2S,3aS,7aR)-(9CI)(301651-24-1)
• EPA Substance Registry System: 3a(4H)-Benzofuranamine,2-ethoxyhexahydro-N-methoxy-,(2S,3aS,7aR)-(9CI)(301651-24-1)

Safety Data

• Hazardous Substances Data: 301651-24-1(Hazardous Substances Data)

Upstream product

• 301651-22-9 2-(1-ethoxy-2-iodo-ethoxy)-cyclohexanone O-methyl-oxime 
• 60308-50-1 2-hydroxycyclohexanone dimer 
• 301651-21-8 2-hydroxy-1-methoxyimine-cyclohexane 

Relevant articles and documents

Cobaloxime-mediated intramolecular radical addition onto oxime functions in the electrolysis media: Formation of mannich base analogues

Addition of the carbon radical generated from α-bromoacetals onto the O-alkyloximes, affording Mannich base analogues, was achieved by the electrolysis in MeOH containing cobaloxime (catalytic) as a mediator at a Zn sacrificial electrode in an undivided cell. Cyclization proceeded stereoselectively in some cases to afford the 2-alkoxy-3-alkyl-4-aminotetrahydrofurans.

5-exo Radical Cyclization onto 3-Alkoxyketimino-1,6-anhydromannopyranoses. Efficient Preparation of Synthetic Intermediates for (-)-Tetrodotoxin

Ketoxime ethers at C3 of 1,6-anhydro-β-D-mannopyranose derivatives were found to be useful 5-exo radical traps of alkyl and vinyl radicals generated at a chain tethered to the C2 hydroxyl group, allowing advanced synthetic intermediates for (-)-tetrodotoxin to be prepared from D-mannose in good overall yield.