302790-85-8

Basic information

• Product Name: 2,5-ANHYDRO-3-DEOXY-3-(3,4-DIHYDRO-5-METHYL-2,4-DIOXO-1(2H)-PYRIMIDINYL)-D-IDITOL
• Synonyms: 2,5-ANHYDRO-3-DEOXY-3-(3,4-DIHYDRO-5-METHYL-2,4-DIOXO-1(2H)-PYRIMIDINYL)-D-IDITOL
• CAS NO: 302790-85-8
• Molecular Formula: C11H16N2O6
• Molecular Weight: 272.255
• Mol File: 302790-85-8.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2,5-ANHYDRO-3-DEOXY-3-(3,4-DIHYDRO-5-METHYL-2,4-DIOXO-1(2H)-PYRIMIDINYL)-D-IDITOL(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-ANHYDRO-3-DEOXY-3-(3,4-DIHYDRO-5-METHYL-2,4-DIOXO-1(2H)-PYRIMIDINYL)-D-IDITOL(302790-85-8)
• EPA Substance Registry System: 2,5-ANHYDRO-3-DEOXY-3-(3,4-DIHYDRO-5-METHYL-2,4-DIOXO-1(2H)-PYRIMIDINYL)-D-IDITOL(302790-85-8)

Safety Data

• Hazardous Substances Data: 302790-85-8(Hazardous Substances Data)

Usage

Derived from

D-iditol

Appearance

White solid

Potential applications

Intermediate in chemical synthesis, biochemical and pharmacological properties

Possible uses in research

Study of carbohydrate chemistry and related fields

Specific application and context dependence

Precise uses and effects may vary depending on the specific application and context in which the compound is employed.

Upstream product

• 495-75-0 2,5-anhydro-D-mannose 
• 41107-82-8 2,5-anhydro-D-mannitol 
• 86363-73-7 (2R,3S,4S,5R)-3,4-dihydroxy(tetrahydrofuran-2,5-diyl)bis(methylene) dibenzoate 
• 1078691-95-8 (+)-D-glucosamine hydrochloride 
• 91318-12-6 2,5:3,4-dianhydro-1,6-di-O-benzoyl-D-altritol 
• 65-71-4 thymin 
• 171877-92-2 2,5:3,4-dianhydro-L-talofuranose dimethylacetal 
• 196596-83-5 3-O-p-tolylsulfonyl-2,5-anhydro-L-idofuranose dimethylacetal 
• 196596-85-7 2,5-anhdyro-4-deoxy-4-(thymin-1-yl)-L-mannofuranose dimethyl acetal 

Relevant articles and documents

Synthesis of 3-deoxy-3-nucleobase-2,5-anhydro-D-mannitol: A novel class of hydroxymethyl-branched isonucleosides

A concise synthesis of 3-deoxy-3-nucleobase-2,5-anhydro-D-mannitol 6(a- d) has been achieved, using the deamination of 2-amino-2-deoxy-D-glucose to construct in one step the sugar skeleton with the desired sense of chirality at each asymmetric center. The selective dibenzoylation of 2,5-anhydro-D- mannitol 9 was investigated, and the key epoxide intermediate 13 was obtained in good yield via an intramolecular Mitsunobu reaction. The process of opening of epoxide 13 by nucleobases appeared to be regioselective. (C) 2000 Elsevier Science Ltd.

Stereoselective synthesis of 4-deoxy-4-nucleobase-2,5-anhydro-L-mannitol derivatives

2,5:3,4-Dianhydro-L-talofuranose dimethylacetal 7 was synthesized from D-glucose in 7 steps. A series of 4-deoxy-4-nucleobase-2,5-anhydro-L-mannitols 13-16 were synthesized regioselectively from 7 in good yields. 6-O-p-Tolylsulfonyl-2,5:3,4-dianhydro-L-ta