Antiferromagnetic ordering in cobalt(ii) and nickel(ii) 1D coordination polymers with the dithioamide of 1,3-benzenedicarboxylic acid
A series of 1D coordination polymers [Co(m-dtab)Cl2]n (1), [Co(m-dtab)Br2]n (2) and [Ni(m-dtab) 2(Br)2]n (3), where m-dtab = the dithioamide of 1,3-benzenedicarboxylic acid, were
Lytvynenko, Anton S.,Kolotilov, Sergey V.,Cador, Olivier,Golhen, Stephane,Ouahab, Lahcene,Pavlishchuk, Vitaly V.
Domino aryne precursor: Efficient construction of 2,4-disubstituted benzothiazoles
An aryne precursor with a potential to perform domino aryne chemistry was proposed and synthesized. The reaction of this reagent with benzothioamide derivatives could afford 2,4-disubstituted benzothiazole with sequential incorporation of C-S, C-N, and C-C bonds on the consecutive three positions of the aryne precursor.
Shi, Jiarong,Qiu, Dachuan,Wang, Juan,Xu, Hai,Li, Yang
supporting information
p. 5670 - 5673
(2015/05/20)
Efficient and green protocol for the synthesis of thioamides in C 6 (mim)2Cl2 as a dicationic ionic liquid
A simple, efficient, facile and eco-friendly process for the synthesis of thioamides from nitriles using 1,6-bis(3methylimidazolium-1-yl)hexane chloride [C6(mim)2Cl2] as a dicationic ionic liquid (DIL) was developed. The ionic liquid was easily separated from the reaction mixture and was recycled at least four times without any loss of its activity.
Khosropour,Noei,Mirjafari
experimental part
p. 752 - 758
(2010/11/04)
TiCl3OTf-[bmim]Br: a novel and efficient catalyst system for chemoselective one-pot synthesis of thioamides from arylaldoximes
The combination of TiCl3OTf with 1-butyl-3-methylimidazolium bromide is found to be an efficient and novel catalytic system for chemoselective one-pot transformation of arylaldoximes to their corresponding thioamides in high to excellent yields.
Noei, Jalil,Khosropour, Ahmad R.
scheme or table
p. 6969 - 6971
(2009/04/07)
QUANTITATIVE RELATIONS BETWEEN CHEMICAL STRUCTURE AND HEPATOTOXICITY OF THIOBENZAMIDES
1H NMR chemical shifts of thioamide protons have been determined for a group of thiobenzamides and the values obtained have been correlated with the Hammett constants.From the relations found the ?m and ?p values of thioamide group a
Waisser, Karel,Machacek, Milos,Lebvoua, Jean,Hrbata, Jiri,Drsata, Jaroslav
p. 2957 - 2961
(2007/10/02)
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