30315-04-9

Basic information

• Product Name: Picrasin B acetate
• Synonyms: Picrasin B acetate
• CAS NO: 30315-04-9
• Molecular Formula: C23H30O7
• Molecular Weight: 418.5
• Mol File: 30315-04-9.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Picrasin B acetate(CAS DataBase Reference)
• NIST Chemistry Reference: Picrasin B acetate(30315-04-9)
• EPA Substance Registry System: Picrasin B acetate(30315-04-9)

Safety Data

• Hazardous Substances Data: 30315-04-9(Hazardous Substances Data)

Usage

Uses

Used in Agriculture:
Picrasin B acetate is used as a natural insecticide for controlling pests such as aphids, mites, and whiteflies. Its application in organic and sustainable agriculture is valued due to its low toxicity to non-target organisms, making it an environmentally friendly option for pest management.
Used in Environmental Protection:
As an eco-friendly alternative to synthetic insecticides, Picrasin B acetate is utilized in environmental protection efforts to minimize the impact of chemical pesticides on non-target species and ecosystems. Its low toxicity profile contributes to the preservation of biodiversity and the health of the environment.

Upstream product

• 26121-56-2 (+)-picrasin B 
• 108-24-7 acetic anhydride 
• 123834-65-1 1β,11β-dihydroxy-16α-methoxy-9β-picrasan-12-one 
• 123834-86-6 (+)-2-deoxypicrasin B 
• 26121-57-3 (+)-Δ²-picrasin B 
• 76-78-8 (+)-quassin 
• 10581-12-1 tetramethyl ammonium acetate 
• 123834-87-7 (3aR,6aR,7aS,8R,10S,11aS,11bS,11cS)-10-Bromo-2-methoxy-3,8,11a,11c-tetramethyl-3a,6a,7,7a,8,9,10,11a,11b,11c-decahydro-4H-6-oxa-benzo[de]anthracene-1,5,11-trione 
• 26121-56-2 nigakilactone I 
• 123834-74-2 7α-hydroxy-8β-(hydroxymethyl)-1β-methoxy-13-methyl-19-nor-9β-podocarp-13-en-12-one 
• 123834-82-2 1β,11β-diacetoxy-20-hydroxy-16-methoxy-9β-picrasan-12-one 
• 127897-16-9 (3R,3aS,6aR,7aS,8R,11aS,11bR,11cS)-5-Methoxy-3,8,11a,11c-tetramethyl-dodecahydro-6-oxa-benzo[de]anthracene-1,2,11-trione 
• 123834-85-5 (3aR,6aR,7aS,8R,11aS,11bS,11cS)-2,5-Dimethoxy-3,8,11a,11c-tetramethyl-3a,4,5,6a,7,7a,8,9,10,11a,11b,11c-dodecahydro-6-oxa-benzo[de]anthracene-1,11-dione 
• 123834-84-4 Acetic acid (1R,3R,3aS,6aR,7aS,8R,11R,11aS,11bR,11cS)-11-acetoxy-5-methoxy-3,8,11a,11c-tetramethyl-2-oxo-hexadecahydro-6-oxa-benzo[de]anthracen-1-yl ester 

Downstream Products

• 26121-56-2 (+)-picrasin B 
• 26121-57-3 (+)-Δ²-picrasin B 

Relevant articles and documents

An Enantioselective Synthesis of (+)-Picrasin B, (+)-Δ2-Picrasin B, and (+)-Quassin from the R-(-) Enantiomer of the Wieland-Miescher Ketone

An enantioselective total synthesis of (+)-picrasin B (1), (+)-Δ2-picrasin B (11), and (+)-quassin (12) from the R-(-) enantiomer of the Wieland-Miescher ketone (3) employed an A-AB-ABC-ABCD sequence to assemble the tetracyclic skeleton.The cru

AN ENANTIOSELECTIVE TOTAL SYNTHESIS OF (+)-PICRASIN B1

An enantioselective total synthesis of (+)-picrasin B (1) from the R-(-)-enantiomer of the Wieland-Miescher ketone (4) employed an A-AB-ABC-ABCD sequence to assemble the tetracyclic skeleton and relied upon a free radical cyclization of an α-bromoacetal to an enone in order to introduce the D ring and a manganese(III) acetate oxidation of a tricyclic enone intermediate in order to introduce the C-11 oxygen substituent.

A PARTIAL SYNTHESIS OF PICRASIN B AND Δ2-PICRASIN B1

The regioselective reductive demethylation of the O-methyldiosphenol functionality in the A ring of quassin (3) with chlorotrimethylsilane and sodium iodide furnished picrasin B (1).Swern oxidation of 1 furnished Δ2-picrasin B (2), and O-methylation of 2 regenerated quassin (3).