Blue LED Irradiation of Iodonium Ylides Gives Diradical Intermediates for Efficient Metal-free Cyclopropanation with Alkenes
A facile and highly chemoselective synthesis of doubly activated cyclopropanes is reported where mixtures of alkenes and β-dicarbonyl-derived iodonium ylides are irradiated with light from blue LEDs. This metal-free synthesis gives cyclopropanes in yields
Chidley, Tristan,Jameel, Islam,Rizwan, Shafa,Peixoto, Philippe A.,Pouységu, Laurent,Quideau, Stéphane,Hopkins, W. Scott,Murphy, Graham K.
supporting information
p. 16959 - 16965
(2019/11/11)
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