309956-58-9Relevant articles and documents
Influence of metal cation on chromophore properties of complexes of some d metals with α,α-dipyrrolylmethene
Guseva,Antina,Berezin,V'yugin
, p. 1282 - 1285 (2007/10/03)
In complexes of Cu2+, Ni2+, Co2+, Zn 2+, and Hg2+ with 3,3′,5,5′-tetramethyl-4, 4′-dibutyl-2,2′-dipyrrolylmethene, the d-metal ion exerts an auxochromic effect on the π system of the ligand, manifested in a bathochromic shift of the first absorption band in the spectrum of the complex, compared to the free ligand. Polarization of the chromophore π system in the complexes increases in the order Zn2+ 2+ 2+ 2+ 2+. The Hg2+ ion in the complex with dipyrrolylmethene participates in mercuration of benzene and chloroform; the reaction with chloroform is faster, with the rates of both reactions strongly depending on temperature. 2004 MAIK Nauka/Interperiodica .