- REACTION OF BIS(2,4,6-TRINITROPHENYL) SULFONE AND ITS DERIVATIVES WITH AMINES
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The reaction of bis(2,4,6-trinitrophenyl) sulfone and some of its 3- and 3,3'-substituted derivatives with organic bases leads to the formation of an adduct of 1,3,5-trinitrobenzene or its substituted derivative and the respective amine, sulfur trioxide, and 2,4,6-trinitrodiphenylamine and its derivatives or derivatives of 2,4,6-trinitroaniline.The direction of reaction does not depend on the ratio of the initial compounds or on the temperature.It was established that attack by the nucleophilic reagent takes place at the ring in which the largest positive charge is induced at the carbon atom attached to the sulfur.
- Nurgatin, V. V.,Sharnin, G. P.,Nurgatina, R. B.,Ginzburg, B. M.
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p. 306 - 309
(2007/10/02)
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