Dichlorodimethylhydantoin-KF as an efficient reagent for one pot synthesis of dialkylfluorophosphates from dialkylphosphites
Organic-inorganic hybrid reagent dichlorodimethylhydantoin-KF (DCDMH-KF) mixture was explored as an efficient reagent for the direct conversion of dialkylphosphites to their corresponding dialkylfluorophosphates at room temperature and in shorter reaction times through a facile electrophilic-nucleophilic metathesis.
Single step fluorination of dialkylphosphites: trichloroacetonitrile-KF as an efficient reagent for the synthesis of dialkyl fluorophosphates
The use of trichloroacetonitrile and KF mixture is described as an efficient reagent for the direct conversion of dialkylphosphites to their corresponding dialkyl fluorophosphates via in situ formation of dialkyl chlorophosphates in one-pot.