Synthesis of bis(trimethylsilyl) ketone and reactions with organometallic compounds
Bis(trimethylsilyl) ketone (1) has been prepared by hydrolysis of the α-chloro ether 3a on silica gel. Reaction of ketone 1 with organoaluminium, organomagnesium and organolithium compounds gave addition products and/or bis(trimethylsilyl)methanol (5). Acta Chemica Scandinavica 1998.
Pan, Ming,Benneche, Tore
p. 1141 - 1143
(2007/10/03)
Einfache nucleophile Silylierungsreaktionen an Carbonylfunktionen mit Trimethylsilylaluminium-Verbindungen
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Roesch, Lutz,Altnau, Gerald,Otto, Wolfgang Helmut
p. 607 - 608
(2007/10/02)
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