311321-58-1Relevant articles and documents
Direct preparation of arylethynylzinc bromides and their application to cross-coupling reactions
Joo, Seong-Ryu,Kim, Jong-Sung,Kim, Seung-Hoi
, p. 3267 - 3270 (2017/07/27)
A novel synthetic protocol for the preparation of arylethynylzinc bromides has been developed. Thus-obtained organozinc reagents were successfully employed in the subsequent cross-coupling reactions with a broad range of aryl halides providing the corresponding alkynylated compounds in good to excellent yields.
A novel access to disubstituted acetylenes
Katritzky, Alan R.,Abdel-Fattah, Ashraf A. A.,Wang, Mingyi
, p. 7526 - 7529 (2007/10/03)
Reactions of organometallic reagents with 1-(substituted ethynyl)-1H-1,2,3-benzotriazoles 5 derived from a variety of benzotriazolylmethyl ketones 3 afforded disubstituted acetylenes in synthetically useful yields.