31208-93-2

Basic information

• Product Name: 2-nitrophenylmaltoside
• Synonyms: 2-nitrophenylmaltoside
• CAS NO: 31208-93-2
• Molecular Formula: C₁₈H₂₅NO₁₃
• Molecular Weight: 463.39
• Mol File: 31208-93-2.mol

Chemical Properties

• Melting Point: 153-155 °C(Solv: ethanol (64-17-5); ethyl ether (60-29-7))
• Boiling Point: 787.5°C at 760 mmHg
• Flash Point: 430.1°C
• Appearance: /
• Density: 1.7g/cm³
• Vapor Pressure: 3.94E-26mmHg at 25°C
• Refractive Index: 1.67
• PKA: 12.56±0.70(Predicted)
• CAS DataBase Reference: 2-nitrophenylmaltoside(CAS DataBase Reference)
• NIST Chemistry Reference: 2-nitrophenylmaltoside(31208-93-2)
• EPA Substance Registry System: 2-nitrophenylmaltoside(31208-93-2)

Safety Data

• Hazardous Substances Data: 31208-93-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C18H25NO13/c20-5-9-11(22)12(23)14(25)18(30-9)32-16-10(6-21)31-17(15(26)13(16)24)29-8-4-2-1-3-7(8)19(27)28/h1-4,9-18,20-26H,5-6H2/t9-,10-,11-,12+,13-,14-,15-,16-,17+,18-/m1/s1

Upstream product

• 77988-25-1 Acetic acid (2R,3R,4S,5R,6R)-3-acetoxy-6-acetoxymethyl-2-(2-nitro-phenoxy)-5-((2R,3R,4S,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-4-yl ester 
• 3616-19-1 1,2,3,6,2',3',4',6'-octa-O-acetylmaltose 
• 7166-81-6 2,3,6-tri-O-acetyl-(2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl)-β-D-glucopyranosyl chloride 

Downstream Products

• 56193-44-3 o-nitrophenyl-α-D-galactopyranoside 

Relevant articles and documents

STEREOSELECTIVE SYNTHESES OF O- AND S-NITROPHENYL GLYCOSIDES. PART III. SYNTHESES IN THE &α-D-GALACTOPYRANOSE AND &α-MALTOSE SERIES

The action of p-nitrophenol penta-O-acetyl-β-D-galactopyranose in dichloromethane, in the presence of stannic tetrachloride gave p-nitrophenyl α-D-galactoside in fair yield.This technique failed when o-nitrophenol was used.Tetra-O-acetyl-β-D-galactopyranosyl and hepta-O-acetyl-β-maltosyl chlorides were converted to p- or o-nitrophenyl α-D-glycosides and p-nitrophenyl α-D-1-thioglycosides in good yield using hexamethylphosphoramide as a solvent and the sodium salt of the phenols as nucleophiles.The galactosides have been functionalized for further condensation at the C-4 position by selective benzoylation.