Synthesis of Sb-chiral organoantimony compounds having intramolecular Sb?N interaction and their separation into optically pure compounds via ortho-palladated benzylamine complexes
A diastereomeric mixture of Sb-chiral triarylstibanes having an amine moiety on an aryl group, Sb(R/S)-(aryl)[2-(S)-(1-dimethylaminoethyl)phenyl] (p-tolyl)stibanes (4a-c), has been prepared by stepwise nucleophilic displacement of the ethynyl groups on bi
ANTIMONY-SULPHUR BONDED COMPOUNDS. IV. FURTHER STUDIES ON THE THERMAL DECOMPOSITION OF TETRA-ORGANOANTIMONY MERCAPTIDES
The thermolytic decompositions of Ph4SbSAr in organic solvents are reported.Solvent-derived products from decompositions in CCl4 and cyclohexane confirm the free radical nature of the reactions.Thermal decompositions of Ph3(p-MeC6H4)SbSC6H4OMe-p, or Ph(p-
Bedi, Bhupinder S.,Grant, Douglas W.,Tewnion, Lesley,Wardell, James L.
p. 251 - 266
(2007/10/02)
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