NUCLEOPHILIC CLEAVAGE AND FORMATION OF SATURATED HETEROCYCLES. IX. KINETICS OF THE AMINATION OF 1-AZIRIDINE
1.Enlarging the aminoethyl substituent at the heteroatom of the aziridine ring results in a decrease in reactivity and an increase in substrate selectivity towards nucleophilic cleavage by amines. 2.The reactivity of amines in the nucleophilic cleavage of 1-aziridine is largely governed by the steric accessibility of the nitrogen atoms of the nucleophile.Amino groups in which the environment of the reaction site is the same have similar reactivities.
Bobylev, V. A.,Dalin, A. R.,Borisenko, I. V.,Kamskaya, O. I.
p. 1003 - 1007
(2007/10/02)
More Articles about upstream products of 31329-52-9