313697-12-0Relevant articles and documents
Preparative procedure of dihalosulfenylation: Thiobisamines addition to unsaturated compounds in the presence of phosphorus oxyhalides and halides
Zyk,Beloglazkina,Vatsadze,Titanyuk,Dubinskaya
, p. 794 - 800 (2007/10/03)
A new synthetic method was developed for β,β′-dihaloalkyl sulfides (halogen chlorine or bromine) by reaction of thiobisamines with olefins and alkynes in the presence of the appropriate phosphorus halides. The reaction proceeds along electrophilic mechanism affording trans-addition products. The highest yields of the target products were obtained at POBr3 or POCl3 application.