Cyclometalated metal-organic frameworks as stable and reusable heterogeneous catalysts for allylic N-alkylation of amines
Metal-organic frameworks (MOFs) functionalized via Ir(i) cyclometalation are shown to be effective as heterogeneous catalysts for the allylic N-alkylation of various amines. The MOF catalysts are one of the first and most effective MOF-based heterogeneous organometallic catalysts for the direct formation of C-N bonds. In addition, these MOFs represent a rare, stable and reusable, class of reactive Ir catalysts. The Royal Society of Chemistry 2013.
Dau, Phuong V.,Cohen, Seth M.
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p. 6128 - 6130
(2013/07/26)
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