A concerted mechanism for the transfer of the thiophosphinoyl group from aryl dimethylphosphinothioate esters to oxyanionic nucleophiles in aqueous solution
Earlier work on the hydrolysis of aryl phosphinothioate esters has led to contradictory mechanistic conclusions. To resolve this mechanistic ambiguity, we have measured linear free energy relationships (βnuc and βIg) and kinetic isot
Onyido, Ikenna,Swierczek, Krzysztof,Purcell, Jamie,Hengge, Alvan C.
p. 7703 - 7711
(2007/10/03)
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