32466-55-0

Basic information

• Product Name: (E)-tridec-2-enoic acid
• Synonyms: (E)-tridec-2-enoic acid;(E)-2-Tridecenoic acid
• CAS NO: 32466-55-0
• Molecular Formula: C₁₃H₂₄O₂
• Molecular Weight: 212.32846
• EINECS: 251-062-2
• Mol File: 32466-55-0.mol

Chemical Properties

• Boiling Point: 327.8°Cat760mmHg
• Flash Point: 231.6°C
• Appearance: /
• Density: 0.917g/cm³
• Vapor Pressure: 3.93E-05mmHg at 25°C
• Refractive Index: 1.464
• CAS DataBase Reference: (E)-tridec-2-enoic acid(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-tridec-2-enoic acid(32466-55-0)
• EPA Substance Registry System: (E)-tridec-2-enoic acid(32466-55-0)

Safety Data

• Hazardous Substances Data: 32466-55-0(Hazardous Substances Data)

Usage

Uses

Used in Chemical Synthesis:
(E)-tridec-2-enoic acid is used as a precursor in the chemical synthesis of various organic compounds, leveraging its unique structural properties to facilitate the creation of a diverse array of molecules.
Used in Polymer Production:
In the polymer industry, (E)-tridec-2-enoic acid serves as a building block for the production of specific types of polymers, contributing to the development of materials with tailored properties for specialized applications.
Used in Insect Pheromone Research:
(E)-tridec-2-enoic acid is utilized in the study and development of insect pheromones, specifically for understanding and manipulating the attraction behaviors of certain moth species, which can have implications in pest control and ecological studies.
Used in Organic Chemistry Research:
As a valuable compound in organic chemistry, (E)-tridec-2-enoic acid is employed in research to explore its potential in various chemical reactions and to enhance the understanding of long-chain unsaturated fatty acids' reactivity and behavior.

InChI:InChI=1/C13H24O2/c1-2-3-4-5-6-7-8-9-10-11-12-13(14)15/h11-12H,2-10H2,1H3,(H,14,15)/b12-11+

Upstream product

• 141-82-2 malonic acid 
• 112-44-7 undecylaldehyde 
• 7069-41-2 (2E)-tridecenal 
• 68480-25-1 trans-2-tridecen-1-ol 
• 638-53-9 tridecanoic acid 

Downstream Products

• 112-70-9 tridecan-1-ol 
• 112-37-8 undecylenic acid 
• 15790-94-0 trans-2-undecenoic acid 

Relevant articles and documents

Allyl-Palladium-Catalyzed α,β-Dehydrogenation of Carboxylic Acids via Enediolates

A highly practical and step-economic α,β-dehydrogenation of carboxylic acids via enediolates is reported through the use of allyl-palladium catalysis. Dianions underwent smooth dehydrogenation when generated using Zn(TMP)2?2 LiCl as a base in the presence of excess ZnCl2, thus avoiding the typical decarboxylation pathway of these substrates. Direct access to 2-enoic acids allows derivatization by numerous approaches.

Selective aerobic oxidation of allylic and benzylic alcohols catalyzed by N-hydroxyindole and copper(I) chloride

In the presence of copper(I) chloride, tert-butyl 1-hydroxy-2-methyl-6- trifluoromethyl-1H-indole-3-carboxylate acted as a catalyst for the chemoselective aerobic oxidation of allylic and benzylic alcohols. A variety of primary and secondary allylic and benzylic alcohols were oxidized into the corresponding α,β-unsaturated carbonyl compounds in good yields without affecting non-allylic alcohols.

INHIBITORS OF YEAST FILAMENTOUS GROWTH AND METHOD OF THEIR MANUFACTURE

The invention broadly relates to the use of α, β-unsaturated fatty acids to inhibit the filamentous growth of fungi and yeasts and to a method for producing same. In particular the invention relates to the use of optionally substituted C8 to C15 α, β-unsaturated fatty acids or salts, esters or amides thereof for inhibiting or retarding the yeast-to-mycelium transition of organisms having a dimorphic life cycle.

Synthesis of (+)-ginnol, a type R(long)-CH(OH)-R'(long) alcohol, by an asymmetric β,γ-unsaturated ester→γ-butyrolactone conversion

An enantioselective synthesis of (+)-ginnol (17) illustrates how Sharpless' asymmetric dihydroxylation may be used for the asymmetric synthesis of monoalcohols. The dihydroxylation was perfomed with AD mix α and the unsaturated ester trans-9. The resulting lactone cis-13 was dehydrated giving butenolide 13 (96.2% ee) from where we proceeded to the title compound 17 in three steps. Butenolide 13 showed 88-94%ee when ester trans-9 contained cis-isomer due to too forcing reaction condition on the way to the precursor acids trans- and cis-7.