HIGH-TEMPERATURE ORGANIC SYNTHESIS XLIII. REACTIONS OF ORGANIC DISELENIDES WITH PROPARGYL ALCOHOL
The gas-phase reaction of propargyl alcohol with dialkyl diselenides at 400 - 430 deg C leads to a high yield of 1,2-diselenol-3-one. 1,2-Diselenol-3-one is formed in a similar way from diphenyl diselenide at 450 - 500 deg C but with a low yield.The mechanism of the thermal dissociation of the diselenides and their reactions with propargyl alcohol is discussed.
Deryagina, E. N.,Korchevin, N. A.,Voronkov, M. G.
p. 1069 - 1072
(2007/10/02)
High-Temperature Synthesis of 1,2-Dithiol-3-One
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Ostroukhova, L. A.,Turchaninova, L. P.,Korchevin, N. A.,Deryagina, E. N.,Voronkov, M. G.
p. 824
(2007/10/02)
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