Catalyst-controlled site-selective N-H and C3-arylation of carbazoleviacarbene transfer reactions
A site-selective direct arylation reaction of carbazole and other N-heterocycles with diazo-naphthalen-2(1H)-ones has been developed. While Au(i)-NHC catalysts lead to selective C3-arylation, palladium acetate allows for selective N-H arylation, displaying complete site-selectivity each. To show the applicability of these arylation reactions, one-pot, two-fold diarylation reactions of carbazole were demonstrated.
Bahukhandi, Srishti Ballabh,Bera, Sourav Sekhar,Empel, Claire,Koenigs, Rene M.
supporting information
p. 6193 - 6196
(2021/06/30)
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