Synthesis of aryloxyacetonitriles based on arylboronic acids with 2-bromoacetonitrile
A new and efficient protocol for the synthesis of aryloxyacetonitriles based on arylboronic acids with 2-bromoacetonitrile has been developed using eco-friendly hydrogen peroxide as oxidant under metal-free conditions. This method is compatible with arylboronic acid attached sensitive substituent and obtains desired product in moderate to good yield.
Effect of the tether length upon Truce-Smiles rearrangement reactions
This report examines the effect of substrate design upon the Truce-Smiles rearrangement, an intramolecular nucleophilic aromatic substitution reaction. The length of the molecular spacer that tethers the carbanion nucleophile to the substituted benzene ri
Fuss, David,Wu, Yu Qi,Grossi, Michael R.,Hollett, Joshua W.,Wood, Tabitha E.
(2017/10/06)
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