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4-IODOBENZALDEHYDE OXIME is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 34158-75-3 Structure
  • Basic information

    1. Product Name: 4-IODOBENZALDEHYDE OXIME
    2. Synonyms: 4-IODOBENZALDEHYDE OXIME;4-IODOBENZALDOXIME;SYN-4-IODOBENZALDEHYDE OXIME
    3. CAS NO:34158-75-3
    4. Molecular Formula: C7H6INO
    5. Molecular Weight: 247.03
    6. EINECS: N/A
    7. Product Categories: Aromatic Hydrazides, Hydrazines, Hydrazones and Oximes
    8. Mol File: 34158-75-3.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 4-IODOBENZALDEHYDE OXIME(CAS DataBase Reference)
    10. NIST Chemistry Reference: 4-IODOBENZALDEHYDE OXIME(34158-75-3)
    11. EPA Substance Registry System: 4-IODOBENZALDEHYDE OXIME(34158-75-3)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 34158-75-3(Hazardous Substances Data)

34158-75-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 34158-75-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,4,1,5 and 8 respectively; the second part has 2 digits, 7 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 34158-75:
(7*3)+(6*4)+(5*1)+(4*5)+(3*8)+(2*7)+(1*5)=113
113 % 10 = 3
So 34158-75-3 is a valid CAS Registry Number.

34158-75-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-iodobenzaldehyde oxime

1.2 Other means of identification

Product number -
Other names 4-iodo-benzaldehyde seqtrans-oxime

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:34158-75-3 SDS

34158-75-3Relevant articles and documents

The local and natural sources in synthetic methods: the practical synthesis of aryl oximes from aryl aldehydes under catalyst-free conditions in mineral water

Goksu, H.,Orhan, E.

, (2021/07/27)

The synthesis of oximes from aryl aldehydes was prepared using hydroxylamine hydrochloride. The obtained oxime compounds were synthesized at maximum efficiency in mineral water at room temperature. The developed method is economical, practical and environmentally friendly. All of the aldehydes were converted the oxime a method using local sources and useful for industrial applications is introduced in the literature. Graphic abstract: In this study, addition elimination reaction, one of the important reactions of organic chemistry, was carried out using local sources. With this reaction, aryl oximes were obtained from aryl aldehydes in mineral water under catalyst-free conditions.[Figure not available: see fulltext.]

Visible-light mediated stereospecific C(sp2)-H difluoroalkylation of (Z)-aldoximes

Chen, Hua,Deng, Hongmei,Gong, Haiying,Hao, Jian,Li, Mingjie,Peng, Yi,Wan, Wen,Wang, Qian,Zhang, Yifang

supporting information, p. 7867 - 7874 (2021/09/28)

A visible light mediated stereospecific C(sp2)-H difluoroalkylation of (Z)-aldoximes to (E)-difluoroalkylated ketoximes has been described. In this reaction, (hetero)-aromatic and aliphatic difluoroalkylated ketoximes could be obtained with the retention of the configuration of the starting aldoximes. A preliminary mechanism study showed that a difluoromethyl radicalviaan SET pathway was involved.

A Transition-Metal-Free One-Pot Cascade Process for Transformation of Primary Alcohols (RCH2OH) to Nitriles (RCN) Mediated by SO2F2

Jiang, Ying,Sun, Bing,Fang, Wan-Yin,Qin, Hua-Li

, p. 3190 - 3194 (2019/05/21)

A new transition-metal-free one-pot cascade process for the direct conversion of alcohols to nitriles was developed without introducing an “additional carbon atom”. This protocol allows transformations of readily available, inexpensive, and abundant alcohols to highly valuable nitriles.

Enantioselective α-Alkylation of Benzylideneamino tert-Butyl Malonates by Phase-Transfer Catalysis

Park, Cheonhyoung,Ha, Min Woo,Kim, Byungsoo,Hong, Suckchang,Kim, Doyoung,Park, Yohan,Kim, Mi-Hyun,Lee, Jae Kyun,Lee, Jeeyeon,Park, Hyeung-Geun

supporting information, p. 2841 - 2848 (2015/09/28)

A new enantioselective synthetic method for the synthesis of α,α-dialkylmalonates with a quaternary carbon center was developed via α-alkylation of prochiral malonates by phase-transfer catalysis (PTC). Asymmetric α-alkylation of benzylideneamino tert-butyl α-methylmalonates under phase-transfer catalytic conditions in the presence of (S,S)-3,4,5-trifluorophenyl-NAS bromide afforded the corresponding α,α-dialkylmalonates in high yields (up to 97%) with excellent enantioselectivities (up to 98% ee). The products were then selectively hydrolyzed to chiral malonic monoacids under basic, acidic, or catalytic hydrogenation conditions.

Synthesis of Nitriles from Aldoximes and Primary Amides Using XtalFluor-E

Keita, Massaba,Vandamme, Mathilde,Paquin, Jean-Fran?ois

, p. 3758 - 3766 (2015/11/28)

The dehydration reaction of aldoximes and amides for the synthesis of nitriles using [Et2NSF2]BF4 (XtalFluor-E) is described. Overall, the reaction proceeds rapidly (normally 1 h) at room temperature in an environmentally benign solvent (EtOAc) with only a slight excess of the dehydrating agent (1.1 equiv). A broad scope of nitriles can be prepared, including chiral nonracemic ones. In addition, in a number of cases, further purification of the nitrile after the workup was not required.

COMPOUNDS USEFUL AS INHIBITORS OF ATR KINASE

-

Page/Page column, (2014/05/07)

The present invention relates to compounds useful as inhibitors of ATR protein kinase. The invention also relates to pharmaceutically acceptable compositions comprising the compounds of this invention; methods of treating of various diseases, disorders, a

A versatile and green mechanochemical route for aldehyde-oxime conversions

Aakeroey, Christer B.,Sinha, Abhijeet S.,Epa, Kanishka N.,Spartz, Christine L.,Desper, John

supporting information, p. 11289 - 11291,3 (2012/12/12)

A robust, facile and solvent-free mechanochemical path for aldehyde-oxime transformations using hydroxylamine and NaOH is explored; the method is suitable for aromatic and aliphatic aldehydes decorated with a range of substituents. This journal is

Discovery, synthesis, and biological evaluation of a novel group of selective inhibitors of filoviral entry

Yermolina, Maria V.,Wang, Jizhen,Caffrey, Michael,Rong, Lijun L.,Wardrop, Duncan J.

experimental part, p. 765 - 781 (2011/04/15)

Herein, we report the development of an antifiloviral screening system, based on a pseudotyping strategy, and its application in the discovery of a novel group of small molecules that selectively inhibit the Ebola and Marburg glycoprotein (GP)-mediated infection of human cells. Using Ebola Zaire GP-pseudotyped HIV particles bearing a luciferase reporter gene and 293T cells, a library of 237 small molecules was screened for inhibition of GP-mediated viral entry. From this assay, lead compound 8a was identified as a selective inhibitor of filoviral entry with an IC50 of 30 μM. To analyze functional group requirements for efficacy, a structure-activity relationship analysis of this 3,5-disubstituted isoxazole was then conducted with 56 isoxazole and triazole derivatives prepared using "click" chemistry. This study revealed that while the isoxazole ring can be replaced by a triazole system, the 5-(diethylamino)acetamido substituent found in 8a is required for inhibition of viral-cell entry. Variation of the 3-aryl substituent provided a number of more potent antiviral agents with IC50 values ranging to 2.5 μM. Lead compound 8a and three of its derivatives were also found to block the Marburg glycoprotein (GP)-mediated infection of human cells.

N-Hydroxy-(4-oxime)-cinnamide: A versatile scaffold for the synthesis of novel histone deacetilase (HDAC) inhibitors

Giannini, Giuseppe,Marzi, Mauro,Pezzi, Riccardo,Brunetti, Tiziana,Battistuzzi, Gianfranco,Marzo, Maria Di,Cabri, Walter,Vesci, Loredana,Pisano, Claudio

scheme or table, p. 2346 - 2349 (2009/12/07)

With the aim to discover novel HDAC inhibitors with high potency and good safety profiles, we have designed a small library based on a N-hydroxy-(4-oxime)-cinnamide scaffold. We describe the synthesis of these novel compounds and some preliminary in vitro

Synthesis and evaluation of isoxazole derivatives as lysophosphatidic acid (LPA) antagonists

Yamamoto, Takashi,Fujita, Koichi,Asari, Sayaka,Chiba, Akira,Kataba, Yuka,Ohsumi, Koji,Ohmuta, Naoko,Iida, Yuko,Ijichi, Chiori,Iwayama, Satoshi,Fukuchi, Naoyuki,Shoji, Masataka

, p. 3736 - 3740 (2008/02/07)

A series of isoxazole derivatives were synthesized and their antagonistic activities against LPA stimulation on both LPA1/CHO cells and rHSC cells were evaluated. Among them, 3-(4-{4-[1-(2-chloro-cyclopent-1-enyl)-ethoxycarbonylamino]-isoxazol-3- yl}-benzylsulfanyl)-propionic acid (34) showed the most potent activities.

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