Model Systems for Flavoenzyme Activity. Control of Flavin Recognition via Specific Electrostatic Interactions
matrix presented A model system has been used to study the interactions of dipole-containing aromatic systems with oxidized and reduced flavin. Ab initio computational and experimental studies show that dipole orientation within the host is a critical determinant for recognition and redox behavior of the flavin guest.
Goodman, Allan J.,Breinlinger, Eric C.,McIntosh, Catherine M.,Grimaldi, Lisa N.,Rotello, Vincent M.
p. 1531 - 1534
(2007/10/03)
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