cas 35005-61-9, 3-AMINO-3-(4-NITROPHENYL)PROPIONIC ACID | Articles data ｜lookchem

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35005-61-9

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Crystal and molecular structure of N-(4-nitrophenyl)-β-alanine - Its vibrational spectra and theoretical calculations
The N-(4-nitrophenyl)-β-alanine in crystalline form directly by the addition of 4-nitroaniline to the acrylic acid in aqueous solution has been obtained. The title β-alanine derivative crystallizes in the P2 1/c space group of monoclinic system with four molecules per unit cell. The X-ray geometry of β-alanine derivative molecule has been compared with those obtained by molecular orbital calculations corresponding to the gas phase. In the crystal the molecules related by an inversion center interact via symmetrically equivalent O-H?O hydrogen bonds with O?O distance of 2.656(2) forming a dimeric structure. The dimers of β-alanine derivative weakly interact via N-H?O hydrogen bonds between the H atom of β-amine groups and one of O atom of nitro groups. The room temperature powder vibrational (infrared and Raman) measurements are in accordance with the X-ray analysis. In aqueous solution of 4-nitroaniline and acrylic acid, the double CC bond of vinyl group of acrylic acid breaks as result of 4-nitroaniline addition.
Marchewka,Drozd,Janczak
p. 758 - 766
(2011)
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Polyclonal antibody-catalysed hydrolysis of a β-lactam
We report the first example of antibody-catalysed hydrolysis of a β-lactam where the antibodies were generated by a simple transition-state analogue; in this example the antibodies are polyclonal.
Ostler, Elizabeth L.,Resmini, Marina,Boucher, Guillaume,Romanov, Nickolas,Brocklehurst, Keith,Gallacher, Gerard
p. 226 - 227
(2002)
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Chemical Properties

Melting Point: 215 °C (dec.)
Boiling Point: 410.3°Cat760mmHg
Flash Point:202°C
Density: 1.404g/cm³
PSA: 95.15000
LogP: 2.07760

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