350610-39-8Relevant articles and documents
Stoichiometric and catalytic reductive aldol cyclizations of alkynediones induced by Stryker's reagent
Chiu, Pauline,Leung, Sze Kar
, p. 2308 - 2309 (2007/10/03)
Conjugate reduction of alkynones by stoichiometric [(Ph3P)CuH] 6 or catalytic [(Ph3P)CuH]6 and polymethylhydrosiloxane proceeds to cyclization by an aldol reaction with tethered ketones to generate β-hydroxyenon
Tandem conjugate reduction-aldol cyclization using stryker's reagent
Chiu, Pauline,Szeto, Chun-Pong,Geng, Zhe,Cheng, Kin-Fai
, p. 1901 - 1903 (2007/10/03)
(formula presentation) Conjugate reduction by Stryker's reagent to form copper enolates, followed by intramolecular aldol cyclization, successfully generated five- and six-membered carbocycles in one pot efficiently. This tandem reaction is generally dias